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Pinner reaction
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Pinner reaction : ウィキペディア英語版
Pinner reaction
The Pinner reaction (after Adolf Pinner) is an organic reaction of a nitrile with an alcohol using an acid catalyst, for instance, hydrochloric acid. The product formed is the hydrochloric acid salt of an imino ester or an alkyl imidate, which sometimes is called a Pinner salt. The reaction is a sequence of nucleophilic additions.
These salts can react with an excess of alcohol to form the orthoester RC(OR)3, with ammonia or an amine to form an amidine or with water to form an ester.
It should be appreciated that the Pinner reaction refers specifically to an acid catalyzed process, but that similar results can often be achieved using base catalysis. The two approaches can be complementary, with nitriles which are unreactive under acid conditions often giving better results in the presence of base, and vice versa. The determining factor is typically how electron-rich or poor the nitrile is. For example: an electron-poor nitrile is a good electrophile (readily susceptible to attack from alkoxides etc.) but a poor nucleophile (difficult to protonate) and would therefore be expected to react more readily under basic rather than acidic conditions.
==See also==

* Overman rearrangement
* Hoesch reaction

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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